Method for the preparation of trans-1, 2-Dichloroethylene
Trans-1, 2-dichloroethylene is a kind of next generation chlorinated solvent which can be widely used in precision electronic instrument cleaning. Compared with traditional chlorinated and brominated solvents, trans-1, 2-dichloroethylene is safe for human health and more friendly to environmental characteristics. At present, the production methods of trans-1, 2-dichloroethylene in the market are mainly as follows: (1) Trans-1, 2-dichloroethylene May be obtained by dechlorination of 1, 1, 2, 2-tetrachloroethane by zinc powder or iron powder, or by cracking of 1, 1, 2-trichloroethane by copper chloride on pumice stone. However, no industrial production has been reported for either method. (2) US patents us20070191653 and us7335806 and world patent wo2007094965 have reported the preparation of trans 1, 2-dichloroethane. The patent is the reaction of 1, 2-dichloroethane with chlorine gas under the action of oxychlorination catalyst to obtain 1, 2-trichloroethane, 1, 2-trichloroethane...